Action of Heat on Substances – Form 2 Chemistry Notes

Sources of Energy

Heating something requires an energy source. The main ones are:

Source Notes Renewable?
Biomass Organic material — grains, wood chips, animal waste; used for heating/cooking Yes
Fossil fuels Coal, crude oil, natural gas — formed from ancient living matter No
Solar Harvested via solar panels Yes
Wind Turbines drive generators Yes
Geothermal Steam from hot rocks beneath the Earth drives turbines Yes
Wave Ocean wave motion drives turbines Yes
Hydro Water from a dam turns generators; costly to build Yes
Nuclear Energy released by nuclear reactions, e.g. from uranium; safety and waste disposal are concerns No

Fossil fuels and biomass both release large amounts of CO₂. Renewable sources are essentially unlimited in supply; non-renewable ones are finite and don’t replenish on a human timescale.

Decomposition vs. Dissociation

When some substances are heated, they break down into two or more new substances that do not recombine on cooling — this is thermal decomposition, e.g. CaCO₃ → CaO + CO₂. If the products do recombine on cooling, it’s called thermal dissociation — a reversible reaction, e.g. NH₃ + HCl ⇌ NH₄Cl.

How Different Substances Respond to Heat

Mass increases when a metal is heated in air and reacts with oxygen to form its oxide — e.g. copper turns from reddish-brown to black as it forms copper(II) oxide: 2Cu + O₂ → 2CuO.

Mass decreases when heating causes decomposition and a gas escapes:

  • Calcium carbonate decomposes to calcium oxide and CO₂ (CaCO₃ → CaO + CO₂) — the released CO₂ turns limewater milky, which is the standard test for the gas. Lithium and magnesium carbonate behave the same way (Li₂CO₃ → Li₂O + CO₂; MgCO₃ → MgO + CO₂).
  • Copper(II) carbonate decomposes from green to black copper(II) oxide: CuCO₃ → CuO + CO₂.
  • Lead(II) nitrate crystals decompose releasing reddish-brown NO₂ gas and oxygen: 2Pb(NO₃)₂ → 2PbO + 4NO₂ + O₂.
  • Lead(IV) oxide decomposes at around 600°C: 2PbO₂ → 2PbO + O₂.
  • Hydrated salts — those with water of crystallisation loosely bound in their structure — lose that water on heating to become anhydrous, e.g. blue CuSO₄·5H₂O becomes white anhydrous CuSO₄. Na₂CO₃·10H₂O and CaSO₄·2H₂O are further examples.
  • Sugar decomposes on heating, losing water and leaving carbon (charcoal) behind, turning from white to black: C₁₂H₂₂O₁₁ → 12C + 11H₂O.

No change in mass occurs for salts that are simply stable to heat and don’t decompose at all, such as NaCl, MgCl₂ and KCl (sodium carbonate, Na₂CO₃, is a further example).

A Few More Useful Terms

  • Water of crystallisation: water molecules loosely bound within a substance’s structure.
  • Anhydrous means without water of crystallisation (e.g. anhydrous calcium chloride); hydrated means it contains water of crystallisation (e.g. CuSO₄·5H₂O); dehydration is the removal of that water.
  • Conductors allow heat or electricity to pass through them (all metals); insulators do not (most non-metals, plastics).
  • Electrolytes are substances that, in solution or molten, allow electricity to pass through while decomposing in the process (e.g. sodium chloride); non-electrolytes do not conduct electricity in this way.

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